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Drawing (1) shows a nonequilibrium system comprised of pure water separated from an aqueous solution by a semipermeable membrane.Shaded spheres represent solute particles and unshaded spheres represent water molecules.Which drawing (2) -(5) represents this system after equilibrium is reached? Drawing (1) shows a nonequilibrium system comprised of pure water separated from an aqueous solution by a semipermeable membrane.Shaded spheres represent solute particles and unshaded spheres represent water molecules.Which drawing (2) -(5) represents this system after equilibrium is reached?   A) drawing (2)  B) drawing (3)  C) drawing (4)  D) drawing (5)


A) drawing (2)
B) drawing (3)
C) drawing (4)
D) drawing (5)

E) A) and B)
F) C) and D)

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Which is not a solution?


A) sterling silver
B) fog
C) hydrochloric acid
D) coffee

E) B) and C)
F) B) and D)

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Commercial cold packs often contain solid NH4NO3 and a pouch of water.The temperature of the pack drops as the NH4NO3 dissolves in water.Therefore,for the dissolving of NH4NO3 in water,


A) ΔHsoln is negative and ΔSsoln may be negative or positive.
B) ΔHsoln is negative and ΔSsoln is positive.
C) ΔHsoln is positive and ΔSsoln may be negative or positive.
D) ΔHsoln is positive and ΔSsoln is positive.

E) C) and D)
F) None of the above

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Which of the following is not an application of colligative properties?


A) adding silver to mercury to lower the vapor pressure of mercury
B) desalinating sea water by reverse osmosis
C) melting snow by application of salt
D) reduced boiling points of pure liquids at increased altitudes

E) B) and C)
F) A) and B)

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The volume of 0.200 M H2SO4 that contains 5.00 mmol of H+ is ________ mL.

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  -Which drawing above represents the system with the second highest entropy? A) drawing (a)  B) drawing (b)  C) drawing (c)  D) drawing (d) -Which drawing above represents the system with the second highest entropy?


A) drawing (a)
B) drawing (b)
C) drawing (c)
D) drawing (d)

E) B) and D)
F) A) and C)

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A gold ring is an example of a ________ solution.


A) gas/gas
B) liquid/solid
C) solid/lliquid
D) solid/solid

E) A) and B)
F) A) and C)

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When KI is dissolved in water,the major forces overcome are ________ forces in the solute and ________ forces in the solvent,and the major forces created between solute and solvent particles are ________ forces.

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ionic bond...

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  -Which drawing above represents the system with the highest entropy? A) drawing (a)  B) drawing (b)  C) drawing (c)  D) drawing (d) -Which drawing above represents the system with the highest entropy?


A) drawing (a)
B) drawing (b)
C) drawing (c)
D) drawing (d)

E) All of the above
F) A) and D)

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  -Which drawing above represents the system with the second lowest entropy? A) drawing (a)  B) drawing (b)  C) drawing (c)  D) drawing (d) -Which drawing above represents the system with the second lowest entropy?


A) drawing (a)
B) drawing (b)
C) drawing (c)
D) drawing (d)

E) None of the above
F) B) and D)

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At 25°C the vapor pressures of benzene and toluene are 96.0 mm Hg and 30.5 mm Hg,respectively.When a 1:1 molar mixture of benzene and toluene is fractionally distilled,the first fraction will have a mole fraction of benzene that is closest to


A) 0.0.
B) 0.5.
C) 0.7.
D) 1.0.

E) A) and C)
F) B) and C)

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Calculate the molality of a solution with 53 grams of KCl in 2000 mL of water.(density of water is 1.00 g/mL) .


A) 0.027
B) 0.27
C) 0.00071
D) 0.0027

E) B) and D)
F) B) and C)

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If one mole of each is dissolved in 1.00 L of water,which will lower the vapor pressure the most?


A) C12H22O11
B) KNO3
C) C3H7OH
D) MgCl2

E) A) and D)
F) All of the above

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For which case would ΔHsoln be expected to be negative?


A) if solute-solute interactions are much greater than solvent-solvent and solute-solvent interactions
B) if solvent-solvent interactions are much greater than solute-solvent and solute-solute interactions
C) if solute-solvent interactions are much greater than solvent-solvent and solute-solute interactions
D) if solute-solvent interactions are the same as solvent-solvent and solute-solute interactions

E) A) and B)
F) None of the above

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For a liquid solution made by dissolving a solid or a gas in a liquid,the


A) liquid is the solute.
B) liquid is the solvent.
C) solute is the component present in the greatest amount.
D) solvent is the component present in the greatest amount.

E) A) and B)
F) None of the above

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A 1.40 M solution of CaCl2 in water has a density of 1.11 g/mL.What is the molality?


A) 1.90 m CaCl2
B) 2.30 m CaCl2
C) 1.47 m CaCl2
D) 1.44 m CaCl2

E) None of the above
F) B) and C)

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Substances with high lattice energies tend to be less soluble than substances with low lattice energies.On that basis predict the relative aqueous solubility at 20°C,from highest to lowest,of the following ionic compounds: Substances with high lattice energies tend to be less soluble than substances with low lattice energies.On that basis predict the relative aqueous solubility at 20°C,from highest to lowest,of the following ionic compounds:   A) Fe<sub>2</sub>(SO<sub>4</sub>) <sub>3</sub> > Li<sub>2</sub>SO<sub>4</sub> > KBr > LiCl B) Fe<sub>2</sub>(SO<sub>4</sub>) <sub>3</sub> > Li<sub>2</sub>SO<sub>4</sub> > LiCl > KBr C) KBr > LiCl > Li<sub>2</sub>SO<sub>4 </sub>> Fe<sub>2</sub>(SO<sub>4</sub>) <sub>3</sub> D) LiCl > KBr > Li<sub>2</sub>SO<sub>4</sub><sub> </sub>> Fe<sub>2</sub>(SO<sub>4</sub>) <sub>3</sub>


A) Fe2(SO4) 3 > Li2SO4 > KBr > LiCl
B) Fe2(SO4) 3 > Li2SO4 > LiCl > KBr
C) KBr > LiCl > Li2SO4 > Fe2(SO4) 3
D) LiCl > KBr > Li2SO4 > Fe2(SO4) 3

E) All of the above
F) None of the above

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The osmotic pressure of a 100-mL solution containing 1.0 g of sucrose,C12H22O11 will be ________ (equal to,greater than,less than)the osmotic pressure of a 100-mL solution containing 1.0 g of fructose,C6H12O6.

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Dinitrogen monoxide is still used as a general anesthetic.The Henry's law constant for the solubility of N2O in water is 2.5 × 10-2 mol/L·atm.What is the molar solubility of N2O in water if the partial pressure of N2O is 1700 mm Hg?

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What is the molality of a glucose solution prepared by dissolving 9.00 g of glucose,C6H12O6,in 125.9 g of water?


A) 2.38 × 10-4 m
B) 0.0715 m
C) 0.347 m
D) 0.397 m

E) All of the above
F) A) and D)

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